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Design of Coordination Polymers based on combinations of 1,2-diphenylethane-1,2-diyl diisonicotinate with Cu(II), Zn(II), Cd(II) and Co(II)

Abstract : Five new supramolecular coordination polymers (L-Cu(acac)2, L-Cu(hfac)2, L-ZnCl2, L-CdI2 and L-CoCl2) based on the use of the flexible organic ligand L (1,2-Diphenylethane-1,2-diyl diisonicotinate) combined with Cu(acac)2, Cu(hfac)2, ZnCl2, CdI2 or CoCl2 metallaligands, were synthesized and structurally characterized by single-crystal X-ray diffraction. They represent the first reported coordination polymers based on this ligand presenting ether junctions. X-ray diffraction analysis revealed the structure and the dimensionality of these coordination polymers as well as their packing in the crystal that depends on the conformation adopted by the ligand L and the nature of the metallic salts
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https://hal-cnrs.archives-ouvertes.fr/hal-03807759
Contributor : Abdelaziz Jouaiti Connect in order to contact the contributor
Submitted on : Wednesday, October 12, 2022 - 3:43:38 PM
Last modification on : Saturday, October 15, 2022 - 4:53:25 AM

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Sofia Zazouli, Nathalie Kyritsakas, Veronique Bulach, Sylvie Ferlay, Abdelaziz Jouaiti. Design of Coordination Polymers based on combinations of 1,2-diphenylethane-1,2-diyl diisonicotinate with Cu(II), Zn(II), Cd(II) and Co(II). CrystEngComm, In press, ⟨10.1039/D2CE01001A⟩. ⟨hal-03807759v2⟩

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