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Direct Synthesis of Vinylene Carbonates from Aromatic Aldehydes

Abstract : Substituted vinylene carbonates were directly prepared from aromatic aldehydes following a one-pot Benzoin condensation/transcarbonation sequence under solvent-free conditions. The combination of a N-phenyl substituted triazolium salt NHC precursor and 4-dimethylaminopyridine (DMAP) was found essential to reach high yield and selectivity. The reaction scope was investigated with a range of aromatic aldehydes and the corresponding vinylene carbonates were obtained with 32–86 % isolated yields (14 examples).
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Contributor : Nicolas Duguet Connect in order to contact the contributor
Submitted on : Wednesday, October 19, 2022 - 3:46:41 PM
Last modification on : Saturday, October 22, 2022 - 5:48:21 AM


Eur. J. Org. Chem. 2022, e2022...
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Killian Onida, Leyli Ibrahimli, Nicolas Duguet. Direct Synthesis of Vinylene Carbonates from Aromatic Aldehydes. European Journal of Organic Chemistry, 2022, 2022 (29), pp.e202200153. ⟨10.1002/ejoc.202200153⟩. ⟨hal-03821395⟩



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