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Rapid synthesis process and characterization for high purity sodium thioantimoniate nonahydrate

Abstract : For the first time, Na3SbS4·9H2O, also known as Schlippe's salt, has been synthesized through high-energy ball milling. This innovative synthesis way allows for obtaining high purity thioantimonate nonahydrate with around 90% yield in only approximately four hours. To validate the synthesis route described herein, the crystal structure has been refined, at room temperature, through high-resolution X-ray diffraction, pair distribution function analysis and energy dispersive spectrometry. Dehydration and rehydration of the compound have also been studied by thermogravimetric analysis and differential scanning calorimetry.
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https://hal-cnrs.archives-ouvertes.fr/hal-03789446
Contributor : Adam Bertrand Connect in order to contact the contributor
Submitted on : Tuesday, September 27, 2022 - 2:00:32 PM
Last modification on : Thursday, September 29, 2022 - 5:03:07 AM

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Adam Bertrand, A. Paecklar, T. Barbier, F. Gascoin. Rapid synthesis process and characterization for high purity sodium thioantimoniate nonahydrate. Dalton Transactions, 2022, 51 (30), pp.11340-11345. ⟨10.1039/D2DT01520J⟩. ⟨hal-03789446⟩

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