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Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages

Abstract : Coordination driven self-assembly of achiral components, i.e., hexa-alkylated truxene ligands (L) with bis-metallic complexes (M2), afforded three chiral face-rotating stereoisomer polyhedra (M6L2). By tuning the length of the alkyl chains as well as the distance between both ligands facing each other in the self-assemblies (M6L2), one can control the diastereomeric distribution between the expected homo- and hetero-chiral structures.
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Contributor : Sebastien GOEB Connect in order to contact the contributor
Submitted on : Friday, September 9, 2022 - 1:55:28 PM
Last modification on : Tuesday, September 27, 2022 - 4:32:53 AM



Amina Benchohra, Simon Séjourné, Antoine Labrunie, Liam Miller, Enzo Charbonneau, et al.. Controlling Chiral Self-Sorting in Truxene-Based Self-Assembled Cages. Inorganics, MDPI AG, 2022, 10 (7), pp.103. ⟨10.3390/inorganics10070103⟩. ⟨hal-03773676⟩



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