New Biobased Polyurethane Materials from Modified Vegetable Oil

Chakib Mokhtari (1) , Fouad Malek (1) , Sami Halila (2) , Mohamed Naceur Belgacem (3) , Ramzi Khiari (3, 4, 5)

1 Université Mohamed 1 Oujda MAROC
2 CERMAV - Centre de Recherches sur les Macromolécules Végétales
3 Grenoble INP - Institut polytechnique de Grenoble - Grenoble Institute of Technology
4 ISET-Nabeul - Higher Institute of Technological Studies [Nabeul]
5 UM - Université de Monastir - University of Monastir

Bio-based polyurethanes (PUs) have been occurred a large attention nowadays. It was found to be an alternative to the petrochemical based materials to the fact of their weak environmental influence, availability, good price and biodegradability. In addition, the nature shows several bio-derived compounds as raw materials for the synthesis of polyols, including the vegetable oils, polyphenol, terpene, and other bio-renewable sources. With the aim to develop a new family of biobased polyurethanes (PUs) via vegetable oils, the elaboration of new Jojoba-based PUs was performed by catalyst-free polycondensation reaction of a synthesized Jojoba diol with various diisocyanates such us toluene diisocyanate (TDI) and isophorone diisocyanate (IPDI). All the compounds were characterized by FTIR and NMR spectroscopies, and their properties were determined by gel permeation chromatography, differential scanning calorimetry and thermogravimetric analysis. The obtained results show renewable vegetable oils-based PUs materials can be preparing using a new environmentally ways and giving various good properties performances.

Domaines: Matériaux; Polymères

Chakib Mokhtari, Fouad Malek, Sami Halila, Mohamed Naceur Belgacem, Ramzi Khiari. New Biobased Polyurethane Materials from Modified Vegetable Oil. Journal of Renewable Materials, 2021, 9 (7), pp.1213-1223. ⟨10.32604/jrm.2021.015475⟩. ⟨hal-03376617⟩