Folding of phosphodiester-linked donor-acceptor oligomers into supramolecular nanotubes in water - Archive ouverte HAL Access content directly
Journal Articles Chemical Communications Year : 2021

Folding of phosphodiester-linked donor-acceptor oligomers into supramolecular nanotubes in water

(1) , (2) , (3) , (2) , (1) , (1) , (1)
1
2
3

Abstract

Inspired by the automated synthesis of DNA on solid support, electron-rich dialkxoynaphthalene dialkoxynaphthalene (DAN) donor and electron-deficient-naphthalene-tetracarboxylic diimide (NDI) acceptor, amphiphilic foldamers have been synthesised from their respective phosphoramidite building blocks. The folding of the phosphodiester-linked hexamer (DAN-NDI)3 revealed in water the formation in water of regular supramolecular nanotubes resulting from the self-assembly of multiple hexamers stabilized by donor/acceptor interactions and solvophobic effect.
Fichier principal
Vignette du fichier
FoldamerChemComm -revisedOK-1.pdf (1 Mo) Télécharger le fichier
Origin : Files produced by the author(s)

Dates and versions

hal-03739371 , version 1 (27-07-2022)

Identifiers

Cite

Kévan Pérez de Carvasal, Nesrine Aissaoui, Gérard Vergoten, Gaëtan Bellot, Jean-Jacques Vasseur, et al.. Folding of phosphodiester-linked donor-acceptor oligomers into supramolecular nanotubes in water. Chemical Communications, 2021, 57 (34), pp.4130-4133. ⟨10.1039/D1CC01064F⟩. ⟨hal-03739371⟩
8 View
22 Download

Altmetric

Share

Gmail Facebook Twitter LinkedIn More