Design of Fe III –Ln III binuclear complexes using compartmental ligands: synthesis, crystal structures, magnetic properties, and ab initio analysis

Cyrille Train (1) , Alexandru Topor , Dan Liu , Catalin Maxim , Ghenadie Novitchi , Zeid Alothman , Abdullah Al-Kahtani , Liviu Ungur , Le Tuan Anh Ho , Liviu Chibotaru , Marius Andruh

1 LNCMI-G - Laboratoire national des champs magnétiques intenses - Grenoble

Rare examples of phenoxido-bridged Fe III –Ln III binuclear complexes are synthesized, and their dynamic and static magnetic properties are rationalized by ab initio calculations.

Domains: Chemical Sciences; Coordination chemistry

Cyrille Train, Alexandru Topor, Dan Liu, Catalin Maxim, Ghenadie Novitchi, et al.. Design of Fe III –Ln III binuclear complexes using compartmental ligands: synthesis, crystal structures, magnetic properties, and ab initio analysis. Journal of Materials Chemistry C, 2021, 9 (33), pp.10912-10926. ⟨10.1039/d1tc00894c⟩. ⟨hal-03472113⟩