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Synthesis and self-assembly of a penta[60]fullerene bearing benzo[ghi]perylenetriimide units

Abstract : A benzo[ghi]perylenetriimide (BPTI) derivative bearing a terminal azido group on the expanded pconjugated backbone has been synthesized and characterized. This promising photo-and electroactive BPTI motif has been used to obtain an original penta(organo)fullerene as a promising multi-electron acceptor system. Our studies show its self-assembly resulting from aggregation via p-p stacking interaction in solution and in the solid state.
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https://hal-cnrs.archives-ouvertes.fr/hal-03446728
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Submitted on : Wednesday, November 24, 2021 - 2:13:59 PM
Last modification on : Sunday, June 26, 2022 - 3:20:57 AM
Long-term archiving on: : Friday, February 25, 2022 - 7:15:18 PM

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Clément Drou, Théo Merland, Antoine Busseau, Sylvie Dabos-Seignon, Antoine Goujon, et al.. Synthesis and self-assembly of a penta[60]fullerene bearing benzo[ghi]perylenetriimide units. RSC Advances, Royal Society of Chemistry, 2021, 11, pp.6002 - 6007. ⟨10.1039/d1ra00287b⟩. ⟨hal-03446728⟩

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